Although I have never worked with spherical camera arrays, I would think each image would have a pitch value of the number of degrees from vertical the camera is mounted, a yaw value equal to the angle the camera is pointed from the front of the car, corrected for the direction the car is pointed when each image is taken, and a roll value of zero assuming the car is traveling flat.
If a camera is mounted pointed to the right side of the vehicle and down 30 degrees from the horizon, and an image was taken when the car was on a compass heading of 225 when an image was taken, the yaw value would be -45 (225+90 = 345 compass which is 45 degrees left of North), the pitch would be 60 (90-30), and the roll would be zero